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We present a general methodology towards the systematic characterization of crystalline topological insulating phases with time reversal symmetry (TRS).~In particular, taking the two-dimensional spinful hexagonal lattice as a proof of principle we study windings of Wilson loop spectra over cuts in the Brillouin zone that are dictated by the underlying lattice symmetries.~Our approach finds a prominent use in elucidating and quantifying the recently proposed ``topological quantum chemistry" (TQC) concept.~Namely, we prove that the split of an elementary band representation (EBR) by a band gap must lead to a topological phase.~For this we first show that in addition to the Fu-Kane-Mele $\mathbb{Z}_2$ classification, there is $C_2\mathcal{T}$-symmetry protected $\mathbb{Z}$ classification of two-band subspaces that is obstructed by the other crystalline symmetries, i.e.~forbidding the trivial phase.
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