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An equilibrium state can be represented by a pure quantum state, which we call a thermal pure quantum (TPQ) state.
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Entropy could be obtained if one could obtain a TPQ state of a huge system which includes the target system. However, this is harder than calculating the partition function
Cited in the paper.
These are the conditions that the Boltzmann formula gives the correct thermodynamic entropy and that the system is stable. Hence, they are necessary for all microscopic models to which statistical mechanics is applied
Cited in the paper.
When A ^ \hat{A} is unbounded, ‖ A ^ ‖ \|\hat{A}\| should be replaced with max | ϕ ⟩ ∈ ℋ N ⊂ | ⟨ ϕ | A ^ | ϕ ⟩ | \max_{|\phi\rangle\in\mathcal{H}_{N}^{\subset}}|\langle\phi|\hat{A}|\phi\rangle| , where ℋ N ⊂ \mathcal{H}_{N}^{\subset} denotes a Hilbert subspace in which the values of macroscopic variables (such as u u and m z m_{z} ) are limited to certain finite ranges
Cited in the paper.
K. Sakai, private communication
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A. Shimizu, J. Phys. Soc. Jpn. 77
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S. Sugiura and A. Shimizu, Proc. Meeting of Phys. Soc. Jpn. 2011, paper number 23aGA-6
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J. Sato et al
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